50th Anniversary Perspective: Metal-Catalyzed Living Radical Polymerization: Discovery and Perspective
50th Anniversary Perspective: Metal-Catalyzed Living Radical Polymerization: Discovery and Perspective
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DOI：
10.1021/acs.macromol.6b02711
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发表时间：
2017-04-11
期刊：
影响因子：
5.5
通讯作者：
Sawamoto, Mitsuo
中科院分区：
文献类型：
--
作者：
Ouchi, Makoto;Sawamoto, Mitsuo
通过可逆活化休眠物种的活性聚合的发展打开了发现金属催化的活性自由基聚合的大门，该活性自由基聚合现在对于精确构建定制的聚合物结构非常有用。在这个纪念性的角度来看，历史方面以及作为一种新的聚合工具的前景描述了先进的结构控制或技术材料创新在各个领域。
Development of living polymerizations via reversible activation of dormant species opened the door to discovery of metal-catalyzed living radical polymerization that is now very useful for precise construction of tailor-made polymeric architectures. In this commemorative Perspective, the historical aspects as well as the prospects as a new polymerization tool are described toward advanced structural control or technological materials innovation in various fields.