Synthesis, Structure, and Solution Equilibria of Diamagnetic and Paramagnetic Azooximates of Bivalent Platinum. Geometrical Change Associated with Ligand-Based Electroprotic Reactions
Synthesis, Structure, and Solution Equilibria of Diamagnetic and Paramagnetic Azooximates of Bivalent Platinum. Geometrical Change Associated with Ligand-Based Electroprotic Reactions
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DOI：
10.1021/ic00104a026
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发表时间：
1994-12
影响因子：
4.6
通讯作者：
C. Pal;Surajit Chattopadhyay;C. Sinha;A. Chakravorty
中科院分区：
文献类型：
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作者：
C. Pal;Surajit Chattopadhyay;C. Sinha;A. Chakravorty
不饱和配体的金属螯合物本身就是容易发生电子转移的潜在位点，因此人们对它们的化学性质有着持久的兴趣。1值得注意的例子是二硫杂环戊烯、2二氧杂环戊烯、3-5和二亚胺。6-12在此，我们介绍偶氮肟螯合体系13 -15 1作为潜在的电保护剂，
There is abiding chemical interest in metal chelates of unsaturated ligands that are themselves potential sites of facile electron transfer.* 1 Notable examples are the dithiolenes, 2 dioxolenes, 3-5 and diimines. 6-12 Herein we introduce the azooxime chelate system13-15 1 as a potential electroproticac-