Single-molecule magnetism of tetrapyrrole lanthanide compounds with sandwich multiple-decker structures

Single-molecule magnetism of tetrapyrrole lanthanide compounds with sandwich multiple-decker structures
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DOI:
10.1016/j.ccr.2015.07.004
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发表时间:
2016
影响因子:
20.6
通讯作者:
Hailong Wang;Bing-wu Wang;Yongzhong Bian;Song Gao;Jianzhuang Jiang
Hailong Wang;Bing-wu Wang;Yongzhong Bian;Song Gao;Jianzhuang Jiang
中科院分区:
化学1区
文献类型:
--
作者:
Hailong Wang;Bing-wu Wang;Yongzhong Bian;Song Gao;Jianzhuang Jiang

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夹心四吡咯系镧系化合物的单分子磁性明显地在纯镧系配位配合物的磁化学中引起了巨大的复兴。在这篇综述中,我们重点介绍了它们的结构-功能关系,它们的历史演变,以及表面效应对多(四吡咯)镧系配合物的SMM性质的初步研究,用于自旋电子器件的开发。
The single-molecule magnetism of sandwich tetrapyrrole lanthanide compounds has clearly initiated a huge renaissance in the magnetochemistry of pure lanthanide coordination complexes. In this review, we focus on their structure–function relationships, their historical evolution, and preliminary efforts in surface effect on the SMM properties of multikis(tetrapyrrole) lanthanide complexes for the development of spintronic devices.