4,4'-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile.
4,4'-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile.
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DOI:
10.1107/s1600536809007284
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发表时间:
2009-03-06
期刊:
影响因子:
--
通讯作者:
Kargar H
中科院分区:
文献类型:
--
作者:
Kia R;Fun HK;Kargar H
The molecule of the title Schiff base compound, C18H14N4, lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine (C=N) bonds. The imino groups are coplanar with the aromatic rings with a maximum deviation of 0.1574 (12) Å for the N atom. Within the molecule, the planar units are parallel, but extend in opposite directions from the dimethylene bridge. In the crystal structure, pairs of intermolecular C—H⋯N hydrogen bonds link neighbouring molecules into centrosymmetric dimers with R 2 2(10) ring motifs. An interesting feature of the crystal structure is the short intermolecular C⋯C interaction with a distance of 3.3821 (13) Å, which is shorter than the sum of the van der Waals radius of a carbon atom.