4,4'-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile.

4,4'-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile.
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DOI:
10.1107/s1600536809007284
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发表时间:
2009-03-06
期刊:
Acta crystallographica. Section E, Structure reports online
影响因子:
--
通讯作者:
Kargar H
Kargar H
中科院分区:
其他
文献类型:
--
作者:
Kia R;Fun HK;Kargar H

文献摘要

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The mol­ecule of the title Schiff base compound, C18H14N4, lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine (C=N) bonds. The imino groups are coplanar with the aromatic rings with a maximum deviation of 0.1574 (12) Å for the N atom. Within the mol­ecule, the planar units are parallel, but extend in opposite directions from the dimethyl­ene bridge. In the crystal structure, pairs of inter­molecular C—H⋯N hydrogen bonds link neighbouring mol­ecules into centrosymmetric dimers with R 2 2(10) ring motifs. An inter­esting feature of the crystal structure is the short inter­molecular C⋯C inter­action with a distance of 3.3821 (13) Å, which is shorter than the sum of the van der Waals radius of a carbon atom.