Recyclable Crosslinked Polymer Networks via One-Step Controlled Radical Polymerization
Recyclable Crosslinked Polymer Networks via One-Step Controlled Radical Polymerization
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DOI：
10.1002/adma.201600871
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发表时间：
2016-08-17
影响因子：
29.4
通讯作者：
Torkelson, John M.
中科院分区：
文献类型：
--
作者：
Jin, Kailong;Li, Lingqiao;Torkelson, John M.
氮氧介导的聚合策略允许从任何含有碳-碳双键的适合于自由基聚合的单体或聚合物一步合成可再循环的交联聚合物材料。具有动态共价键的所得材料在多次熔融后处理循环后可显示出完全的性能恢复。这种一步到位的策略提供了交联聚合物的稳健的、相对可持续的可回收性和用于先进技术的网络设计。
A nitroxide-mediated polymerization strategy allows one-step synthesis of recyclable crosslinked polymeric materials from any monomers or polymers that contain carbon-carbon double bonds amenable to radical polymerization. The resulting materials with dynamic covalent bonds can show full property recovery after multiple melt-reprocessing recycles. This one-step strategy provides for both robust, relatively sustainable recyclability of crosslinked polymers and design of networks for advanced technologies.