Light Scattering in Solutions of Serum Albumin: Effects of Charge and Ionic Strength1,2
Light Scattering in Solutions of Serum Albumin: Effects of Charge and Ionic Strength1,2
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血清白蛋白溶液中的光散射：电荷和离子强度的影响1,2
DOI：
10.1021/ja01166a085
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发表时间：
1950
影响因子：
15
通讯作者：
P. Morrison
中科院分区：
文献类型：
--
作者：
J. Edsall;H. Edelhoch;R. Lontie;P. Morrison
发现某些活性亚甲基化合物与苯甲醛的缩合速率依次为：CNCH_2-COOC_2 H_6（66），CH_3COCH_2COOC_2 H_6（22），C_6 H_6-CH_2NO_2（1.2），H_2C（COOC_2 H_6）_2（1），C_6 H_6CH_2-COCH_3（0.58）和C_6 H_6COCH_2C_6 H_5（0.56）。括号中的数字是相对反应性的定量测量。丙二酸酯与苯甲醛的缩合反应速率按以下顺序逐渐降低：p-CH_3O_C_6H_4CHO，p-CH_3O_C_6H_4CHO，p-CH_3O_C_3H_4CHO。整体跌幅约为40%。这些反应的机制。还参见Coombs和Evans，J. Chem. Soc.，1295（1940）号决议。
It has been found that the rates of condensa-tion of certain active methylenecompounds with benzaldehyde decreased in the order: CNCH2-COOC2H6 (66), CH3COCH2COOC2H6 (22), C6H6-CH2N02 (1.2), H2C (COOC2H6) 2 (1), C6H6CH2-COCH3 (0.58) and C6H6COCH2C6H5 (0.56). The numbers in parentheses are a quantitative measure of the relative reactivities. The rates of conden-sation of malonic ester with benzaldehydes de-creased only gradually in the order:/>-CH3OCe-H4CHO, CeHsCHO,£-ClC6H4CHO and p-02N C3H4CHO. The over-all decrease was about 40%. mechanism of these reactions. Also see Coombs and Evans, J. Chem. Soc., 1295 (1940).