Porous organic cage crystals: characterising the porous crystal surface.

Porous organic cage crystals: characterising the porous crystal surface.
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DOI:
10.1039/c2cc36602a
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发表时间:
2012-11
影响因子:
4.9
通讯作者:
Michael J. Bojdys;T. Hasell;N. Severin;K. Jelfs;J. Rabe;A. Cooper
Michael J. Bojdys;T. Hasell;N. Severin;K. Jelfs;J. Rabe;A. Cooper
中科院分区:
化学2区
文献类型:
--
作者:
Michael J. Bojdys;T. Hasell;N. Severin;K. Jelfs;J. Rabe;A. Cooper

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多孔结晶固体的表征通常依赖于单晶X射线衍射,其不能给出关于材料表面的直接信息。在这里,晶体的多孔有机笼,CC3-R,通过原子力显微镜进行了研究,并显示具有两个不同的气-固界面,证明散装晶体结构被保存在多孔晶体表面。
The characterisation of porous crystalline solids often relies on single crystal X-ray diffraction, which does not give direct information about the surface of the material. Here, crystals of a porous organic cage, CC3-R, are investigated by atomic force microscopy and shown to possess two distinct gas-solid interfaces, proving that the bulk crystal structure is preserved at the porous crystal surface.