New Orthorhombic Phase in the Ru–B and Os–B Systems

New Orthorhombic Phase in the Ru–B and Os–B Systems
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DOI:
10.1063/1.1733309
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发表时间:
1962-10
影响因子:
4.4
通讯作者:
R. Roof;C. P. Kempter
R. Roof;C. P. Kempter
中科院分区:
化学2区
文献类型:
--
作者:
R. Roof;C. P. Kempter

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通过使用单晶和多晶X射线衍射技术,(空间群No.59)在Ru-B和Os-B系统中发现,晶格参数为a0=4.6443±0.0003 A,b 0 =2.8668±0.0008 A,c 0 =4.0449±0.0004 A和a0=4.6832±0.0001 A,b0=2.8717±0.0002 A,c0=4.0761±0.0001 A。可能的经验公式是RuB 2和OsB 2,每个晶胞有两个公式权重。
By the use of single crystal and polycrystalline x‐ray diffraction techniques, isomorphous orthorhombic lattices (space group No. 59) have been found in the Ru‐B and Os‐B systems having lattice parameters of a0=4.6443±0.0003 A, b0=2.8668±0.0008 A, c0=4.0449±0.0004 A and a0=4.6832±0.0001 A, b0=2.8717±0.0002 A, c0=4.0761±0.0001 A, respectively. The probable empirical formulas are RuB2 and OsB2, with two formula weights per unit cell.