Recent advances in B-H functionalization of icosahedral carboranes and boranes by transition metal catalysis
Recent advances in B-H functionalization of icosahedral carboranes and boranes by transition metal catalysis
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过渡金属催化二十面体碳硼烷和硼烷的B-H功能化研究进展
DOI：
10.1515/pac-2017-1202
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发表时间：
2018-04-01
影响因子：
1.8
通讯作者：
Duttwyler, Simon
中科院分区：
文献类型：
--
作者：
Duttwyler, Simon
二十面体硼团簇的功能化研究在过去几年中取得了重大进展，导致在各个研究领域的应用越来越多。B-H键直接转化为取代的顶点构成了合成具有所需性质的笼状化合物的有吸引力的策略。本文介绍了过渡金属催化的中性和阴离子硼团簇的B-H活化的最新进展。
Significant progress in the functionalization of icosahedral boron clusters has been made in the past years, leading to an increasing number of applications in various fields of research. The direct conversion of B-H bonds to substituted vertices constitutes an attractive strategy to synthesize cage compounds with desired properties. In this report, recent advances in the transition metal-catalyzed B-H activation of neutral and anionic boron clusters are presented.