Through-Space Magnetic Interaction of cis-Azobenzene Biradical
Through-Space Magnetic Interaction of cis-Azobenzene Biradical
复制标题
顺式偶氮苯双自由基的空间磁相互作用
DOI:
10.1021/acs.cgd.2c01247
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发表时间:
2023
期刊:
影响因子:
--
通讯作者:
Rui Tamura
中科院分区:
文献类型:
--
作者:
Yoshiaki Uchida;Kenjiro Hino;Tatsuhisa Kato;Rui Tamura
Two chiral PROXYL groups bridged with azobenzene show the change of the magnetic properties with thetrans-cisphotoisomerization of the azobenzene moiety. The isomerization brought the radicals closer together and increased the exchange interactions. The spin state of thecis-isomer was determined from two-dimensional nutation spectra as a mixture ofS=1/2andS= 1. This is an example of the optical control of through-space intramolecular magnetic interactions.
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