Non-adiabatic Reactions. Rotation about the Double Bond*
Non-adiabatic Reactions. Rotation about the Double Bond*
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DOI：
10.1021/ja01848a012
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发表时间：
1941-03
影响因子：
15
通讯作者：
J. Magee;W. Shand;H. Eyring
中科院分区：
文献类型：
--
作者：
J. Magee;W. Shand;H. Eyring
I.介绍了关于烯键旋转的顺-反异构化反应的实验结果，表明这些反应可以很好地分为两类。1它们都是一级反应，速率常数约为104 exp。25，000/和10 nexp.
I. Introduction The experimental results of the cis-trans isom-erization reactions which involve rotation about ethylenic double bonds show that these reactions are divided quite well into two classes. 1 They are both first order reactions, and have rate constants approximately 104 exp.—25,000/and 10nexp.