Diastereo-selective synthesis of CF3-substituted epoxide via in situ generated trifluoroethylideneiodonium ylide
Diastereo-selective synthesis of CF3-substituted epoxide via in situ generated trifluoroethylideneiodonium ylide
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DOI：
10.1016/j.gresc.2022.07.005
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发表时间：
2022-07
期刊：
影响因子：
--
通讯作者：
Chenxin Ge;Chao Chen
中科院分区：
文献类型：
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作者：
Chenxin Ge;Chao Chen
The first example for the generation of 2,2,2-trifluoroethylidene ylide from corresponding iodonium salt is reported, which has been successfully applied in the epoxidation of aldehydes, achieving the corresponding trifluoromethylated epoxides in high yields and diastereo-selectivities.
