General Approach for Constructing Mechanoresponsive and Redox-Active Metal-Organic and Covalent Organic Frameworks by Solid-Liquid Reaction: Ferrocene as the Versatile Function Unit
General Approach for Constructing Mechanoresponsive and Redox-Active Metal-Organic and Covalent Organic Frameworks by Solid-Liquid Reaction: Ferrocene as the Versatile Function Unit
复制标题
通过固液反应构建机械响应和氧化还原活性金属有机和共价有机框架的通用方法：二茂铁作为多功能功能单元
DOI：
10.1021/acs.inorgchem.0c00558
复制
发表时间：
2020
影响因子：
4.6
通讯作者：
Feng Luo
中科院分区：
文献类型：
--
作者：
Xue Feng Feng;Wen Hui Yin;Ya Ling Fan;Meng Jia Yin;Zhen Zhen Xu;Feng Luo
我们报告的第一次建设机械响应和氧化还原活性的金属有机框架（MOFs）和共价有机框架（COFs）的锚定二茂铁（Fc）作为机械载体在孔壁的悬垂。这项工作概述了一个简单的，一般的，和低成本的路线来定制的MOFs和COFs的Fc单元的机械响应性质，铁离子的释放，氧化还原行为，和调制的骨架电荷在一起。
We report for the first time the construction of mechanoresponsive and redox-active metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) by anchoring ferrocene (Fc) pendants as mechanophores in the pore wall. This work outlines a simple, general, and low-cost route to tailor MOFs and COFs by a Fc unit for mechanoresponsive nature, the release of Fe ions, redox behavior, and modulation of the skeleton charge together.