Dye-sensitized Solar Cells Consisting of CuI-containing Gels

Dye-sensitized Solar Cells Consisting of CuI-containing Gels
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DOI:
10.1246/cl.2006.444
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发表时间:
2006-03
期刊:
影响因子:
1.6
通讯作者:
T. Kado;Kuniko Soeda;K. Negoro;S. Hayase
T. Kado;Kuniko Soeda;K. Negoro;S. Hayase
中科院分区:
化学4区
文献类型:
--
作者:
T. Kado;Kuniko Soeda;K. Negoro;S. Hayase

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报道了用于染料敏化太阳能电池的含Cul的凝胶。含Cul的凝胶由Cul、碘化甲基丙基咪唑鎓、碘和由聚乙烯基吡啶和四(碘甲基)苯组成的胶凝剂组成。在碘化甲基丙基咪唑鎓的存在下,效率随着碘分子量的增加而增加,这与先前在不存在碘化甲基丙基咪唑鎓的情况下的报道不同。通过胶凝剂的交联反应进行粘性Cul层的固化,而不降低光伏性能。
Cul-containing gels for dye-sensitized solar cells are reported. Cul-containing gels consist of Cul, methylpropylimidazolium iodide, iodine, and gelators consisting of polyvinylpyridine and tetra(iodomethyl)benzene. The efficiency increases with an increase in the amount of iodine molecules in the presence of methylpropylimidazolium iodide, which is different from the previous reports in the absence of methylpropylimidazolium iodide. Solidification of the sticky Cul layers is carried out by cross-linking reaction of gelators without decreasing the photovoltaic performances.