Electrochemistry of lanthanum and uranium chlorides in organic media: Deposition of lanthanum and uranium

Electrochemistry of lanthanum and uranium chlorides in organic media: Deposition of lanthanum and uranium
复制标题

有机介质中氯化镧和氯化铀的电化学:镧和铀的沉积

DOI:
10.1023/a:1020465318857
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发表时间:
2002
影响因子:
1.6
通讯作者:
C. Jérôme
C. Jérôme
中科院分区:
化学4区
文献类型:
--
作者:
L. Martinot;L. Lopes;J. Marien;C. Jérôme

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Molten salts have been widely used for the electrochemical preparation of lanthanum and uranium metals at high temperature. In this paper we demonstrate the feasibility of a similar process in dimethylformamide (DMF) and in the mixture g-butyrolactone/tetrahydrofuran (g-BL/THF). The best conditions for the preparation were deduced from preliminary transient electrochemistry experiments and from secondary ions mass spectrometry (SIMS) measurements involving SIMS mappings and SIMS depth profile analyses.