Ru(bpy)33+ Electrochemiluminescence Detection of Aliphatic and Aromatic Amines with Diketene

Ru(bpy)33+ Electrochemiluminescence Detection of Aliphatic and Aromatic Amines with Diketene
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Ru(bpy)33 双烯酮电化学发光检测脂肪族和芳香族胺

DOI:
10.1246/cl.2003.98
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发表时间:
2003
期刊:
影响因子:
1.6
通讯作者:
K. Uchikura
K. Uchikura
中科院分区:
化学4区
文献类型:
--
作者:
K. Uchikura

文献摘要

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提出了一种基于Ru(bpy)32+衍生化电化学发光(ECL)检测脂肪胺和芳香胺的新方法。使用双乙烯酮将样品胺衍生为乙酰乙酰酰胺型衍生物。通过反相HPLC和ECL检测使用Ru(bpy)32+检测衍生物。
A new derivatization method for the detection of aliphatic and aromatic amines, based on electro-chemiluminescence (ECL) with Ru(bpy)32+ is proposed. Sample amines were derivatized to acetoacetylamide-type derivatives using diketene. The derivatives were detected by reversed-phase HPLC with ECL detection using Ru(bpy)32+.