Structure—Function Analyses of Solar Fuels Catalysts Using in situ X‐Ray Scattering
Structure—Function Analyses of Solar Fuels Catalysts Using in situ X‐Ray Scattering
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利用原位 X 射线散射对太阳能燃料催化剂进行结构-功能分析
DOI：
10.1002/chin.201323250
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发表时间：
2013
期刊：
影响因子：
--
通讯作者：
D. Tiede
中科院分区：
文献类型：
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作者：
Karen L. Mulfort;Anusree Mukherjee;O. Kokhan;Pingwu Du;D. Tiede
本教程综述阐述了解决结构-功能关系的机会，以帮助开发用于太阳能转换的新材料，使用光谱学和催化测量与 X 射线散射分析相结合，提供太阳能燃料催化剂的原位结构表征。作为一个例子，简要回顾了分子钴肟催化剂在双分子和超分子光催化质子还原方案中的应用。这些突出表明需要开发用于太阳能燃料催化的新型模块化、分层、自修复超分子结构。详细讨论了光催化功能背景下非晶材料的 X 射线散射结构分析的示例。
This tutorial review illustrates opportunities for the resolution of structure–function relationships to aid in the development of new materials for solar energy conversion using a combination of spectroscopy and catalysis measurements with X-ray scattering analyses to provide in situ structural characterization of solar fuels catalysts. As an example, the use of molecular cobaloxime catalysts in bimolecular and supramolecular photocatalysis schemes for proton reduction is briefly reviewed. These highlight the need to develop new modular, hierarchical, self-healing supramolecular architectures for solar fuels catalysis. Examples of the X-ray scattering structural analysis of amorphous materials in the context of photocatalytic function are discussed in detail.