The monoanionic pincer-metal platform: a scaffold for meeting challenges in catalysis and materials research.
The monoanionic pincer-metal platform: a scaffold for meeting challenges in catalysis and materials research.
复制标题
单阴离子钳金属平台：应对催化和材料研究挑战的支架。
DOI：
10.1039/c1dt90120f
复制
发表时间：
2011
影响因子：
4
通讯作者：
R. K. Gebbink
中科院分区：
文献类型：
--
作者：
G. Koten;R. K. Gebbink
1976年，Shaw和莫尔顿报道了一种钳形镍化合物，其中镍原子被单阴离子保持在适当的位置，当时，这些作者无法想象，35年后，道尔顿学报的主题问题将致力于描述有机金属化学的新发展的论文，其特征是钳平台作为决定钳的反应性和选择性的关键因素复杂的参与。本期的客座编辑很荣幸被邀请组织这期关于Pincer金属化学的主题期刊，并感谢许多作者通过提交他们的最新成果，接受了展示他们使用这个“特权”配体平台的魅力的机会（见图1），并分享了他们对该领域现状及其快速发展的看法。
In 1976, Shaw and Moulton reported on a pincer–nickel compound with the nickel atom held in place by a monoanionic, terdentate PCP ligand.1 At that time these authors could not have imagined that 35 years later a Dalton Transactions themed issue would be devoted to papers describing novel developments in organometallic chemistry featuring the pincer platform as a crucial factor determining reactivity and selectivity of the pincer complexes involved. The Guest Editors of this issue feel honoured to have been invited to organize this themed issue on Pincer Metal Chemistry and are grateful that somany authors, by submitting their newest achievements, accepted the opportunity to showcase their fascination for using this “privileged” ligand platform (see Fig. 1) and share their views concerning the current status of the field and its rapid development.