Hydrolysis preparation of the compact TiO2 layer using metastable TiCl4 isopropanol/water solution for inorganic-organic hybrid heterojunction perovskite solar cells

Hydrolysis preparation of the compact TiO2 layer using metastable TiCl4 isopropanol/water solution for inorganic-organic hybrid heterojunction perovskite solar cells
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利用亚稳态 TiCl4 异丙醇/水溶液水解制备无机-有机杂化异质结钙钛矿太阳能电池致密 TiO2 层

DOI:
10.1088/1674-4926/36/7/074003
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发表时间:
2015-07-01
影响因子:
5.1
通讯作者:
Wu Ni
Wu Ni
中科院分区:
物理与天体物理4区
文献类型:
--
作者:
Dai Xiaoyan;Shi Chengwu;Wu Ni

文献摘要

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采用水解法制备致密的TiO 2层,以新鲜的亚稳态TiCl 4异丙醇/水溶液为前驱体制备无机-有机混合异质结钙钛矿太阳能电池。以2 mol/L的TiCl 4与异丙醇按1:3的体积比稀释的水溶液为前驱液,制备的TiO 2膜层均匀致密,膜厚为126 nm。相应的钙钛矿太阳能电池给出了10.61%的光伏转换效率。
A hydrolysis process was applied to prepare the compact TiO2 layer using the fresh metastable TiCl4 isopropanol/water solution as the precursor solution for the preparation of the inorganic-organic hybrid heterojunction perovskite solar cells. The optimal compact TiO2 layer prepared from the aqueous solution of 2 mol/L TiCl4 diluted in isopropanol at 1 : 3 by volume as precursor solution was uniform and with a film thickness of 126 nm. The corresponding perovskite solar cell gave a photovoltaic conversion efficiency of 10.61%.