Catalytic oxidation and flow detection of carbohydrates at ruthenium dioxide modified electrodes.
Catalytic oxidation and flow detection of carbohydrates at ruthenium dioxide modified electrodes.
复制标题
二氧化钌修饰电极上碳水化合物的催化氧化和流量检测。
DOI：
10.1021/ac00213a013
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发表时间：
1990
影响因子：
7.4
通讯作者：
Taha,Z
中科院分区：
文献类型：
--
作者：
Wang,J;Taha,Z
0003-2700/90/0362-1413 $02.50/0 detection for liquid chromatography or flow injection systems. Common amperometric detectors, based on glassy carbon or carbon paste electrodes, exhibit no response for carbohydrates. Metallic sensing electrodes have thus been used in place of carbon surfaces. Most commonly, pulsed-amperometric de-tection at platinum or gold electrodes, which incorporates cleaning and activation steps along with detection, has gained wide acceptance and commercialization (1, 2). Chemically modified electrodes (CMEs), containing surface-bound redox mediators, have been employed for minimizing overvoltage effects at carbon surfaces. Santos and Baldwin (3) reported a dual-pulse detection of carbohydrates at cobalt phthalocyanine containing carbon paste electrodes. A recent work by the same group (4) has shown that copper-based CMEs yield a stable response for carbohydrates without recourse to a potential pulse sequence.
