Enzymatic reactions in supercritical CO2:: carboxylation, asymmetric reduction and esterification

Enzymatic reactions in supercritical CO2:: carboxylation, asymmetric reduction and esterification
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DOI:
10.1016/j.cattod.2004.06.111
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发表时间:
2004-10-05
期刊:
影响因子:
5.3
通讯作者:
Nakamura, K
Nakamura, K
中科院分区:
化学2区
文献类型:
--
作者:
Matsuda, T;Watanabe, K;Nakamura, K

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在过去的十年中,超临界二氧化碳的催化反应受到越来越多的关注。本报告回顾了超临界 CO2 中的酶反应,例如脱羧酶对吡咯的羧化、醇脱氢酶对酮的不对称还原以及脂肪酶对三氟甲醇的对映选择性酯化。 (C) 2004 Elsevier B.V. 保留所有权利。
Catalytic reactions in supercritical CO2 have been receiving increased attention during the last decade. This report reviews enzymatic reactions in supercritical CO2 such as carboxylation of pyrrole by a decarboxylase, asymmetric reduction of ketones by an alcohol dehydrogenase and enantioselective esterification of a trifluoromethyl alcohol by a lipase. (C) 2004 Elsevier B.V. All rights reserved.