SYNTHESIS OF D TRANSITION-METAL SULFIDES FROM AMORPHOUS DITHIOOXAMIDE COMPLEXES
SYNTHESIS OF D TRANSITION-METAL SULFIDES FROM AMORPHOUS DITHIOOXAMIDE COMPLEXES
复制标题
DOI：
10.1006/jssc.1994.1073
复制
发表时间：
1994-03-01
影响因子：
3.3
通讯作者：
MOSSET, A
中科院分区：
文献类型：
--
作者：
ABBOUDI, M;MOSSET, A
六种过渡金属或后过渡金属的硫化物已被分解成无定形二硫代氧酰胺配合物。热解的最佳工艺是在动态真空条件下，在680℃的温度下加热4小时。这种制备，没有任何添加的硫化气氛，导致无碳硫化物。
Sulfides of six transition or post-transition metals have been prepared by decomposition of amorphous dithiooxamide complexes. The best procedure of pyrolysis corresponds to a heating at 680°C under a dynamic vacuum during 4 hr. This preparation, without any added sulfurizing atmosphere, leads to carbon-free sulfides.