One-dimensional Raman spectroscopy and shadowgraphy for the analysis of the evaporation behavior of acetone/water drops

One-dimensional Raman spectroscopy and shadowgraphy for the analysis of the evaporation behavior of acetone/water drops
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用于分析丙酮/水滴蒸发行为的一维拉曼光谱和阴影成像

DOI:
10.1016/j.ijheatmasstransfer.2015.05.053
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发表时间:
2015
影响因子:
5.2
通讯作者:
A. Braeuer
A. Braeuer
中科院分区:
工程技术2区
文献类型:
--
作者:
J. Quiño;T. Hellwig;M. Griesing;W. Pauer;H.-U. Moritz;S. Will;A. Braeuer

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本文报告-环境条件下-实验确定的表面回归率的声悬浮丙酮/水滴作为一个函数的混合物组成在下降的边界。作为液滴悬浮的流体是丙酮和水的混合物,在环境条件下蒸气压分别为24.5kPa和3.17kPa。如预期的,丙酮从丙酮/水滴中蒸发得比水快。已经少量的丙酮在混合物中显着增加的表面回归率的drop.Temporally和空间分辨的组合物配置文件进行了测量沿着线通过滴使用一维拉曼光谱。获得了蒸发液滴的阴影图,并由此导出了液滴的收缩率。由于一维拉曼实验具有良好的空间(120 μm)和时间(1 s)分辨率,可以跟踪液滴径向成分分布的演变,表明液滴内部的扩散过程在二元蒸发过程中起着重要作用。
This paper reports – for ambient conditions – experimentally determined surface regression rates of acoustically levitated acetone/water drops as a function of the mixture composition at the drop boundary. The fluid levitated as a drop was a mixture of acetone and water with vapor pressures of 24.5 kPa and 3.17 kPa, respectively, at ambient conditions. As expected the acetone evaporated faster from the acetone/water drop than water. Already small quantities of acetone in the mixture significantly increased the surface regression rate of the drop.Temporally and spatially resolved composition profiles were measured along a line through the drops using one-dimensional Raman spectroscopy. Shadowgraphs of the evaporating drops were acquired, from which the drop shrinkage was derived. Due to the good spatial (120 μm) and temporal (1 s) resolution of the one-dimensional Raman experiment the evolution of the radial composition profiles through the drop could be followed showing that the diffusion-process inside the drop plays an important role in the binary evaporation process.
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