Role of copper species in the oxidative dimerization of arylboronic acids:: Synthesis of symmetrical biaryls
Role of copper species in the oxidative dimerization of arylboronic acids:: Synthesis of symmetrical biaryls
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DOI：
10.1021/jo034680a
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发表时间：
2003-12-26
影响因子：
3.6
通讯作者：
Emrullahoglu, M
中科院分区：
文献类型：
--
作者：
Demir, AS;Reis, Ö;Emrullahoglu, M
某些Cu（I）和Cu（II）盐能够介导芳基硼酸在DMF中的二聚。它们以中等至非常好的产率提供相应的对称联芳基。可以在氧气氛下催化进行反应而没有显著的产率损失。
Certain Cu(I) and Cu(II) salts are able to mediate the dimerization of arylboronic acids in DMF. They provide the corresponding symmetrical biaryls in moderate to very good yields. It is possible to run the reaction catalytically under an oxygen atmosphere without a significant loss of yields.