Reversible 100% linkage isomerization in a single-crystal to single-crystal transformation: photocrystallographic identification of the metastable [Ni(dppe)(eta1-ONO)Cl] isomer.
Reversible 100% linkage isomerization in a single-crystal to single-crystal transformation: photocrystallographic identification of the metastable [Ni(dppe)(eta1-ONO)Cl] isomer.
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DOI：
10.1002/anie.200901706
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发表时间：
2009-07
影响因子：
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通讯作者：
M. Warren;S. Brayshaw;A. Johnson;S. Schiffers;P. Raithby;T. Easun;M. George;J. Warren;S. Teat
中科院分区：
文献类型：
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作者：
M. Warren;S. Brayshaw;A. Johnson;S. Schiffers;P. Raithby;T. Easun;M. George;J. Warren;S. Teat
通过亚硝酸盐：对[Ni (dppe)(η - 1- no2) Cl]的拉曼和单晶光晶体学研究，首次发现了一个在固态下经历100%可逆转化为亚稳态异构体的体系，在这种情况下是[Ni (dppe)(η - 1- ono) Cl]异构体。©2009 Wiley-VCH Verlag GmbH & Co. KGaA。
Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni (dppe)(η1-NO2) Cl] have, for the first time, identified a system which undergoes a reversible 100% conversion into the metastable isomer in the solid state, in this case the [Ni (dppe)(η1-ONO) Cl] isomer.© 2009 Wiley-VCH Verlag GmbH & Co. KGaA.