Application of hydrophilic ionic liquids as co-solvents in chloroperoxidase catalyzed oxidations
Application of hydrophilic ionic liquids as co-solvents in chloroperoxidase catalyzed oxidations
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DOI：
10.1016/j.tetlet.2006.05.072
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发表时间：
2006-07-17
影响因子：
1.8
通讯作者：
Pieraccini, Daniela
中科院分区：
文献类型：
--
作者：
Chiappe, Cinzia;Neri, Lisa;Pieraccini, Daniela
通过动力学和立体化学研究考察了亲水性离子液体对氯过氧化物酶（CPO）活性的影响。采用这种酶在合成的可能性已被证明在几个柠檬酸盐缓冲液-IL混合物中的苯甲硫醚的氧化的化学和立体选择性调查。(c)2006爱思唯尔有限公司版权所有。
The effect of hydrophilic ionic liquids (ILs) on the activity of chloroperoxidase (CPO) was checked through kinetic and stereochemical studies. The possibility to employ this enzyme in synthesis has been demonstrated investigating the chemo- and stereo selectivity of oxidation of phenyl methylsulfide in several citrate buffer-IL mixtures. (c) 2006 Elsevier Ltd. All rights reserved.