Enhanced formaldehyde selectivity in catalytic methane oxidation by vanadia on Ti-doped SBA-15

Enhanced formaldehyde selectivity in catalytic methane oxidation by vanadia on Ti-doped SBA-15
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掺钛 SBA-15 上氧化钒提高甲醛催化氧化的选择性

DOI:
10.1039/c5ra10624a
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发表时间:
2015
期刊:
影响因子:
3.9
通讯作者:
S. Wohlrab
S. Wohlrab
中科院分区:
化学3区
文献类型:
--
作者:
P. Wallis;E. Schönborn;V. N. Kalevaru;Andreas Martin;S. Wohlrab

文献摘要

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将钒物种 (2.5 wt% V) 负载在 0.2 wt% Ti 掺杂 SBA-15 (V/Ti-SBA-15) 上,并测试甲烷选择性氧化为甲醛的情况。与纯 SBA-15 (V/SBA-15) 上的 VOx 相比,V/Ti-SBA-15 在所有转化中显示出改进的氧化还原性能和对甲醛的更高选择性。
Vanadia species (2.5 wt% V) were supported on 0.2 wt% Ti-doped SBA-15 (V/Ti-SBA-15) and tested towards the selective oxidation of methane to formaldehyde. V/Ti-SBA-15 shows improved redox properties and higher selectivity towards formaldehyde over all conversions compared to VOx on pure SBA-15 (V/SBA-15).