Enhanced Li Storage Stability Induced by Locating Sn in Metal-Organic Frameworks.
Enhanced Li Storage Stability Induced by Locating Sn in Metal-Organic Frameworks.
复制标题
将锡置于金属有机框架中可增强锂的储存稳定性
作者:
Wu Na;Wang Wei;Kou Lu-Qing;Zhang Xue;Shi Ya-Ru;Li Tao-Hai;Li Feng;Zhou Jing-Ming;Wei Yu
By locating elemental Sn in an open anionic framework, the particle cracking arising from huge volume expansion of Sn-based anode materials during lithiation/delithiation is alleviated, and the cycling stability is greatly improved. The Sn-based metal-organic framework anode material shows superior cyclic stability, with a capacity retention >92 % (after 200 cycles) and high lithium storage capacity (610 mAh g-1 ).
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