Infrared and Raman Spectra of ClF3 and BrF3

Infrared and Raman Spectra of ClF3 and BrF3
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ClF3 和 BrF3 的红外和拉曼光谱

DOI:
10.1063/1.1673515
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发表时间:
1970
影响因子:
4.4
通讯作者:
J. Holloway
J. Holloway
中科院分区:
化学2区
文献类型:
--
作者:
H. Selig;H. H. Claassen;J. Holloway

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本文研究了卤间化合物ClF_3和BrF_3在气相中的红外光谱和拉曼光谱。每个分子的六个基本振动的频率已经基于C2ν对称性被指定。ClF 3的频率分别为752.1、529.3、328(a1)、702、442(b1)和328(b2)cm−1。对于BrF 3,它们分别为675、552和242(a1)、612和350(b1)以及242(b2)cm-1。
The infrared and Raman spectra of the interhalogens ClF3 and BrF3 have been studied in the vapor phase. Frequencies for the six fundamental vibrations of each molecule have been assigned based on C2ν symmetry. For ClF3 the frequencies are 752.1, 529.3, and 328 (a1), 702 and 442 (b1), and 328 (b2) cm−1. For BrF3 they are 675, 552, and 242 (a1), 612 and 350 (b1), and 242 (b2) cm−1.