Peroxo-Bridged Dinuclear Cobalt(III) Complexes Containing N-Glycoside Ligands from Tris(2-aminoethyl)amine and d-Glucose or Maltose
Peroxo-Bridged Dinuclear Cobalt(III) Complexes Containing N-Glycoside Ligands from Tris(2-aminoethyl)amine and d-Glucose or Maltose
复制标题
含有来自三（2-氨基乙基）胺和 d-葡萄糖或麦芽糖的 N-糖苷配体的过氧桥双核钴 (III) 配合物
DOI：
10.1021/ic9809310
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发表时间：
1999
影响因子：
4.6
通讯作者：
S. Yano
中科院分区：
文献类型：
--
作者：
T. Tanase;T. Onaka;M. Nakagoshi;I. Kinoshita;K. Shibata;M. Doe;Junko Fujii;S. Yano
过氧桥双核钴(III)络合物[{Co((d-Glc)2-tren)}2(μ-O2)]X3·5H2O (X = Cl (2·5H2O), Br (3·5H2O))和[{Co((Mal)2-tren)}2(μ-O2)]Cl3·6H2O (4·6H2O)由以下物质制备CoX2·6H2O、三(2-氨基乙基)胺和 d-葡萄糖 (d-Glc) 或麦芽糖 (α-d-吡喃葡萄糖基-(1→4)-d-葡萄糖；Mal)，并通过元素分析、紫外可见吸收、圆二色性、1H 和 13C NMR 光谱技术以及 X 射线吸收和晶体分析进行表征，其中 (醛糖)2-tren是双(N-醛糖基-2-氨基乙基)(2-氨基乙基)胺(醛糖=d-Glc，Mal)。通过X射线晶体学确定2和4的结构由两个通过过氧单元桥接的Co(III)离子组成： 2·4H2O·CH3OH，斜方晶系，P212121（No.19），a = 19.384（8）A，b = 23.468（5）A，c = 13.195（5）A，V = 6002(2) A3，Z = 4，Dcalcd = 1.440 g cm-3，T = −99 °C，R = 0.078，Rw = 0.085，对于 4961 次反射，I > 3σ(I)； 4·2.25H2O·3.75CH3OH，单斜晶系，P21（4号），a = 12.819(7) A，b = 49.168(18) A，c = 14.973(6) A，β = 104.59(4)°，V...
Peroxo-bridged dinuclear cobalt(III) complexes, [{Co((d-Glc)2-tren)}2(μ-O2)]X3·5H2O (X = Cl (2·5H2O), Br (3·5H2O)) and [{Co((Mal)2-tren)}2(μ-O2)]Cl3·6H2O (4·6H2O), were prepared from CoX2·6H2O, tris(2-aminoethyl)amine, and d-glucose (d-Glc) or maltose (α-d-glucopyranosyl-(1→4)-d-glucose; Mal), and were characterized by elemental analysis, UV−vis absorption, circular dichroism, 1H and 13C NMR spectroscopic techniques, and X-ray absorption and crystallographic analyses, where (aldose)2-tren is bis(N-aldosyl-2-aminoethyl)(2-aminoethyl)amine (aldose = d-Glc, Mal). The structure of 2 and 4 were determined by X-ray crystallography to consist of two Co(III) ions bridged by a peroxo unit: 2·4H2O·CH3OH, orthorhombic, P212121 (No. 19), a = 19.384(8) A, b = 23.468(5) A, c = 13.195(5) A, V = 6002(2) A3, Z = 4, Dcalcd = 1.440 g cm-3, T = −99 °C, R = 0.078, Rw = 0.085 for 4961 reflections with I > 3σ(I); 4·2.25H2O·3.75CH3OH, monoclinic, P21 (No. 4), a = 12.819(7) A, b = 49.168(18) A, c = 14.973(6) A, β = 104.59(4)°, V...