Lanthanoid single-ion magnets with the LnN10 coordination geometry
Lanthanoid single-ion magnets with the LnN10 coordination geometry
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DOI：
10.1039/c6cc01695b
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发表时间：
2016-01-01
影响因子：
4.9
通讯作者：
Tong, Ming-Liang
中科院分区：
文献类型：
--
作者：
Jiang, Zhong-Xia;Liu, Jun-Liang;Tong, Ming-Liang
We have reported two unprecedented single-ion magnets (SIMs) with the homoatomic LnN(10) coordination geometry, where the central Ln (Ln = Dy-III or Er-III) ion is interlocked by two pentadentate ligands (N-5) affording a low symmetry polyhedron. Studies of dynamic magnetic behaviours show an effective energy of 79(4) K for [Dy(N-5)(2)](3+) and 59(4) K for [Er(N-5)(2)](3+), respectively.
