Adsorption and catalytic properties of the inner nanospace of a gigantic ring-shaped polyoxometalate cluster.
Adsorption and catalytic properties of the inner nanospace of a gigantic ring-shaped polyoxometalate cluster.
复制标题
DOI：
10.1002/anie.200903142
复制
发表时间：
2009-11
影响因子：
--
通讯作者：
S. Noro;R. Tsunashima;Y. Kamiya;K. Uemura;H. Kita;L. Cronin;T. Akutagawa;Takayoshi Nakamura
中科院分区：
文献类型：
--
作者：
S. Noro;R. Tsunashima;Y. Kamiya;K. Uemura;H. Kita;L. Cronin;T. Akutagawa;Takayoshi Nakamura
由于其独特的性质，如吸附，分离，交换和催化，这些都与功能性纳米空间的存在有关，因此引起了极大的兴趣。在这方面，聚氧乙烯酸盐簇，这是纳米级的金属氧化物大阴离子建立从分子前体具有一系列的ofunique氧化还原和酸性的性质，是理想的适合于功能nanospaces的发展，但尚未被thesothesexplored。
are of great interestbecause of their unique properties such as adsorption,separation, exchange, and catalysis, which are all associatedwith the presence of a functional nanospace. In this respect,polyoxometalate clusters, which are nanosized metal-oxidemacroanions built from molecular precursors with a range ofunique redox and acidic properties, are ideally suited for thedevelopment of functional nanospaces but have not yet beenthus explored.