Catalytic hydrosilylation of carbonyl compounds with cationic oxorhenium(V) salen
Catalytic hydrosilylation of carbonyl compounds with cationic oxorhenium(V) salen
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DOI：
10.1021/om060503z
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发表时间：
2006-09-25
期刊：
影响因子：
2.8
通讯作者：
Abu-Omar, Mahdi M.
中科院分区：
文献类型：
--
作者：
Du, Guodong;Abu-Omar, Mahdi M.
高价阳离子氧合铼（V）salen配合物在温和的开瓶条件下有效地催化有机硅烷还原羰基化合物。甲硅烷基保护的醇在一个步骤中获得良好至优异的产率，并且各种官能团是相容的。
High-valent cationic oxorhenium(V) salen complexes efficiently catalyze the reduction of carbonyl compounds by organosilanes under mild, open-flask conditions. Good to excellent yields of silyl-protected alcohols are obtained in one step, and a variety of functional groups are compatible.