A novel fused metallaborane cluster formed via gold-phosphorus bond cleavage: the crystal structure of [{HFe4(CO)12BH}2Au][Au(PPh2Me)2]
A novel fused metallaborane cluster formed via gold-phosphorus bond cleavage: the crystal structure of [{HFe4(CO)12BH}2Au][Au(PPh2Me)2]
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通过金磷键断裂形成的新型稠合金属硼烷簇：[{HFe4(CO)12BH}2Au][Au(PPh2Me)2]的晶体结构
DOI：
10.1039/c39880001630
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发表时间：
1988
期刊：
影响因子：
--
通讯作者：
M. Shongwe
中科院分区：
文献类型：
--
作者：
C. Housecroft;A. Rheingold;M. Shongwe
[HFe 4（CO）12 BH][（Ph 3 P）2N]与Me 2 PhPAuCl或MePh 2 PAuCl反应的产物是簇[{HFe 4（CO）12 BH}2Au][AuL 2]（L = PPh 2 Me或PPhMe 2），其阴离子含有两个由裸金原子连接的含硼四铁蝶形片段;连接产物而不是简单的[HFe 4（CO）12{Au（PR 3}BH]型单金（I）衍生物的形成取决于膦取代基。
A product of the reaction of [HFe4(CO)12BH][(Ph3P)2N] with Me2PhPAuCl or MePh2PAuCl is the cluster [{HFe4(CO)12BH}2Au][AuL2](L = PPh2Me or PPhMe2), the anion of which contains two tetrairon butterfly, boron containing, fragments linked by a naked gold atom; the formation of the linked product rather than a simple monogold(I) derivative of type [HFe4(CO)12{Au(PR3}BH] is shown to depend upon the phosphine substituent.