Cavitands with revolving doors regulate binding selectivities and rates in water
Cavitands with revolving doors regulate binding selectivities and rates in water
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DOI：
10.1021/ja058727g
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发表时间：
2006-03-29
影响因子：
15
通讯作者：
Rebek, J
中科院分区：
文献类型：
--
作者：
Hooley, RJ;Van Anda, HJ;Rebek, J
制备了一种水溶性自折叠腔体，其开口端附着四个苯甲酸酯基团。这些苯甲酸盐就像快速进入腔体的“旋转门”。空腔体对小疏水客体的选择性增加，客体交换速率减慢。
A water-soluble self-folding cavitand has been prepared, featuring four benzoate groups attached to the open end. These benzoates act as rapidly “revolving doors” to the cavity. The cavitand shows increased selectivity for small hydrophobic guests and slower rates of guest exchange.