Rovibrational analysis of an intermolecular hydrogen‐bonded vibration: The ν16 band of HCN‐‐‐HF
Rovibrational analysis of an intermolecular hydrogen‐bonded vibration: The ν16 band of HCN‐‐‐HF
复制标题
分子间氢键振动的旋转振动分析：HCN-‐‐HF 的 ν16 能带
DOI：
--
复制
发表时间：
1986
期刊：
影响因子：
--
通讯作者：
W. J. Lafferty
中科院分区：
文献类型：
--
作者：
B. A. Wofford;M. W. Jackson;J. Bevan;W. Olson;W. J. Lafferty
获得了杂二聚体ν-Hf分子间弯曲振动的红外光谱，其分辨率为0.010 cm−-1，并对该带的转动结构进行了指认。ν16态在Cm−1中的光谱常数为：ν0=550.0285(2)；B6=0.117 652 9(10)；D6J=0.2791(5)×10−6；q6=0.579(8)×10−4；α6=−0.002 137(1)，其中引用的不确定度为一个标准差。
The infrared spectrum of the intermolecular bending vibration, the ν16 band, of the heterodimer HCN‐‐‐HF has been obtained with 0.010 cm−1 resolution, and the rotational structure of this band has been assigned. The spectroscopic constants of the ν16 state in cm−1 are: ν0=550.0285(2); B6=0.117 652 9(10); D6J =0.2791(5)×10−6; q6=0.579(8)×10−4; α6=−0.002 137(1), where the uncertainties cited are one standard deviation.