Transient cyclic voltammetry: new theoretical challenges to bring up to date a famous electrochemical lady

Transient cyclic voltammetry: new theoretical challenges to bring up to date a famous electrochemical lady
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瞬态循环伏安法:新的理论挑战让一位著名的电化学女士与时俱进

DOI:
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发表时间:
2020
影响因子:
2.5
通讯作者:
C. Amatore
C. Amatore
中科院分区:
工程技术4区
文献类型:
--
作者:
A. Oleinick;I. Svir;C. Amatore

文献摘要

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与大多数其他电分析方法相比,循环伏安法已经证明了它在研究电化学机理和动力学方面的通用性。许多教科书提供了理解和量化伏安图中显示的主要特征的线索,但不幸的是,当面对目前研究的复杂机制时,这并不经常有用。这篇简短的评论文章揭示了一些需要解决的理论挑战,以研究与循环伏安法的现代应用相关的问题。
Cyclic voltammetry has proven its versatile popularity compared with most other electroanalytical methods for investigating electrochemical mechanisms and kinetics. Many textbooks provide clues for understanding and quantify the main features displayed in a voltammogram, but this is unfortunately not often useful when confronted to intricate mechanisms as those presently investigated. This brief opinion article discloses a few theoretical challenges that need to be solved to investigate issues associated with modern applications of cyclic voltammetry.