A non-equilibrium free energy theorem for deterministic systems
A non-equilibrium free energy theorem for deterministic systems
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DOI：
10.1080/0026897031000085173
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发表时间：
2003-05-20
影响因子：
1.7
通讯作者：
Evans, DJ
中科院分区：
文献类型：
--
作者：
Evans, DJ
Jarzynski和Crooks最近表明，平衡自由能差可以从非平衡热力学路径积分计算。在本文中，我们给出了一个新的推导这个特殊的关系。我们的推导对时间可逆确定性系统是有效的，突出了非平衡自由能定理和涨落定理之间的密切关系。
Jarzynski and Crooks have recently shown that equilibrium free energy differences can be computed from non-equilibrium thermodynamic path integrals. In the present paper we give a new derivation of this extraordinary relation. Our derivation which is valid for time reversible deterministic systems highlights the close relationship between the non-equilibrium free energy theorems and the fluctuation theorem.