Composition and Characterization of Thermoregulated Fiber Containing Acrylic-Based Copolymer Microencapsulated Phase-Change Materials (MicroPCMs)

Composition and Characterization of Thermoregulated Fiber Containing Acrylic-Based Copolymer Microencapsulated Phase-Change Materials (MicroPCMs)
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含丙烯酸基共聚物微胶囊相变材料(MicroPCM)的温控纤维的组成和表征

DOI:
10.1021/ie404174a
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发表时间:
2014-03
期刊:
Industrial & Engineering Chemistry Research
影响因子:
--
通讯作者:
Zhang Xingxiang
Zhang Xingxiang
中科院分区:
其他
文献类型:
--
作者:
Jiang Nan;Zhang Rong;Han Na;Zhang Xingxiang

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我们将正十八烷与丙烯酸酯类共聚物壳层进行微胶囊化,然后在高温高压下对得到的微胶囊进行处理。用场发射扫描电子显微镜(FE-SEM)、透射电子显微镜(TEM)和热重分析(TGA)研究了微囊的形貌和热稳定性的影响。采用熔融纺丝法制备了包埋微胶囊相变材料的聚乙烯纤维基质。采用湿法纺丝方法纺制了含微相变纤维的海藻酸盐纤维,探讨了微相变纤维与海藻酸盐基质金属离子的协同络合作用。最后,以包埋微相变材料的海藻酸纤维为芯材,以聚氨基甲酸酯为护套,制备了芯-鞘结构的温控纤维。本文还对这些温控纤维的形态、结构和热性能进行了研究。
We microencapsulated n-octadecane with acrylic-based copolymer shell and subsequently treated the obtained microcapsules under high temperature and pressure. The effects on morphology and thermal stability of the microcapsules were investigated using field emission scanning electron microscopy (FE SEM), transmission electron microscopy (TEM), and thermogravimetric analysis (TGA). Polyethylene fiber matrixes embedded with microencapsulated phase-change materials (microPCMs) were obtained by melting spinning. Alginate fiber containing microPCMs were spun with a wet-spinning method, and the concerted metal ion complexation of alginate matrix and microPCMs shell was discussed. In the end, the core–sheath structure thermoregulated fibers were fabricated, which were composed of alginate fiber embedded with microPCMs as core and polyurethane as sheath. The morphology, structure, and thermal properties of these thermoregulated fibers were also investigated in this paper present.
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