BiCl3-catalyzed propargylic substitution reaction of propargylic alcohols with C-, O-, S- and N-centered nucleophiles.
BiCl3-catalyzed propargylic substitution reaction of propargylic alcohols with C-, O-, S- and N-centered nucleophiles.
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DOI：
10.1039/b606470a
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发表时间：
2006-08
影响因子：
4.9
通讯作者：
Zhuang-Ping Zhan;Wen-zhen Yang;Rui-feng Yang;Jingxun Yu;Jun-ping Li;Hui-juan Liu
中科院分区：
文献类型：
--
作者：
Zhuang-Ping Zhan;Wen-zhen Yang;Rui-feng Yang;Jingxun Yu;Jun-ping Li;Hui-juan Liu
在BiCl_3催化下，炔丙醇与烯丙基三甲基硅烷、醇、芳香族化合物、硫醇和酰胺等碳原子和杂原子为中心的亲核试剂发生取代反应，生成C-C、C-O、C-S和C-N键。
A general and efficient BiCl3-catalyzed substitution reaction of propargylic alcohols with carbon and heteroatom-centered nucleophiles such as allyl trimethylsilane, alcohols, aromatic compounds, thiols and amides, leading to the construction of C-C, C-O, C-S and C-N bonds, has been developed.