Palladium-Catalyzed Regio- and Stereoselective Reduction of Allylic Compounds with LiHBEt3. Application to the Synthesis of Co-enzyme Q10
Palladium-Catalyzed Regio- and Stereoselective Reduction of Allylic Compounds with LiHBEt3. Application to the Synthesis of Co-enzyme Q10
复制标题
钯催化 LiHBEt3 对烯丙基化合物进行区域选择性和立体选择性还原。
DOI：
--
复制
发表时间：
1986
期刊：
影响因子：
--
通讯作者：
YamazakiKeiji
中科院分区：
文献类型：
--
作者：
MohriMitsunobu;KinoshitaHideki;InomataKatsuhiko;KotakeHiroshi;TakagakiHidetsugu;YamazakiKeiji
在催化量的[PdCl2（dppp）]存在下，烯丙基砜与LiHBEt3的区域和立体选择性双酰化反应成功地应用于辅酶Q10的合成.结果发现，这种还原系统是适用于各种各样的烯丙基官能团。
Regio- and stereoselective desulfonylation of allylic sulfones with LiHBEt3 in the presence of a catalytic amount of [PdCl2(dppp)] was successfully applied to the synthesis of co-enzyme Q10. It was found that this reduction system was applicable to a wide variety of allylic functional groups.