A new simple route to deoxyamino sugars from non-sugar material:: synthesis of D-tolyposamine and 4-epi-D-tolyposamine and formal synthesis of D-vicenisamine
A new simple route to deoxyamino sugars from non-sugar material:: synthesis of D-tolyposamine and 4-epi-D-tolyposamine and formal synthesis of D-vicenisamine
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DOI：
10.1016/j.tetlet.2005.09.195
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发表时间：
2005-12-05
影响因子：
1.8
通讯作者：
Kino, J
中科院分区：
文献类型：
--
作者：
Matsushima, Y;Kino, J
一种新的，简单的策略已制定的合成脱氧氨基糖从非糖的起始材料。以山梨酸乙酯经Sharpless不对称双羟基化反应得到的对映体纯二醇为原料，合成了2种2，3，4，6-四脱氧-4-氨基糖-D-甲苯泊沙胺和4-表-D-甲苯泊沙胺，并进行了2，4，6-三脱氧-4-氨基糖-D-维森尼沙胺的形式合成。(c)2005爱思唯尔有限公司保留所有权利。
A new, simple strategy has been formulated for the synthesis of deoxyamino sugars from a non-sugar starting material. Starting from the enantiomerically pure diol obtained from ethyl sorbate by Sharpless asymmetric dihydroxylation, the synthesis of two types of 2,3,4,6-tetradeoxy-4-amino sugars-D-tolyposamine and 4-epi-D-tolyposamine-, and formal synthesis of 2,4,6-trideoxy-4-amino sugar-D-vicenisamine-were performed. (c) 2005 Elsevier Ltd. All rights reserved.