A divergent approach to the myriaporones and tedanolide: completion of the carbon skeleton of myriaporone 1.
A divergent approach to the myriaporones and tedanolide: completion of the carbon skeleton of myriaporone 1.
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DOI：
10.1021/ol026356s
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发表时间：
2002-08
期刊：
影响因子：
5.2
通讯作者：
Richard E. Taylor;B. Hearn;J. Ciavarri
中科院分区：
文献类型：
--
作者：
Richard E. Taylor;B. Hearn;J. Ciavarri
[reaction: see text] A linear but concise synthetic approach toward the structurally related natural products myriaporone and tedanolide is reported. The route is highlighted by a stereoselective homoallenylboration and a regio- and chemoselective nitrile oxide cycloaddition. Installation of the (Z)-olefin completed the carbon skeleton of myriaporone 1.
