Metal-catalyzed radical polyaddition as a novel polymer synthetic route
Metal-catalyzed radical polyaddition as a novel polymer synthetic route
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DOI：
10.1039/b616598b
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发表时间：
2007-01-01
影响因子：
4.9
通讯作者：
Kamigaito, Masami
中科院分区：
文献类型：
--
作者：
Satoh, Kotaro;Mizutani, Masato;Kamigaito, Masami
通过金属催化C-C键形成自由基加成，发展了一类新的聚合反应；这些单体被设计成具有活性的C- cl键，可以被金属催化剂激活生成一个碳自由基，以及一个碳- cl -C双键，由另一个分子生成的碳自由基与碳- cl双键加在一起，形成具有非活性C- cl吊坠的C-C主链聚合物。
A new class of polymerizations was developed via metalcatalyzed C-C bond forming radical polyaddition; the monomers were designed to have a reactive C-Cl bond, which can be activated by the metal catalysts to generate a carbon radical species, along with a C L C double bond, to which the carbon radical generated from another molecule adds to form a C-C backbone polymer with an inactive C-Cl pendant.