N 1s x-ray absorption study of the bonding interaction of bi-isonicotinic acid adsorbed on rutile TiO2(110)
N 1s x-ray absorption study of the bonding interaction of bi-isonicotinic acid adsorbed on rutile TiO2(110)
复制标题
金红石TiO2(110)吸附双异烟酸键合相互作用的N 1s X射线吸收研究
DOI：
10.1063/1.480945
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发表时间：
2000
影响因子：
4.4
通讯作者：
L. Patthey
中科院分区：
文献类型：
--
作者：
P. Persson;S. Lunell;P. Brühwiler;J. Schnadt;S. Södergren;J. O'Shea;O. Karis;H. Siegbahn;N. Mårtensson;M. Bässler;L. Patthey
用实验和量子化学方法研究了二异烟酸(2，2‘-联吡啶-4，4’-二羧酸)在金红石型TiO2110表面的N 1S X射线吸收光谱。多层光谱和单层光谱之间的差异可以用吸附在基板上的键来解释。建立了与染料敏化电化学器件中的电子耦合的连接。
N 1s x-ray absorption spectra of bi-isonicotinic acid (2,2′-bipyridine–4,4′-dicarboxylic acid) on rutile TiO2(110) have been studied experimentally and quantum chemically. Differences between multilayer and monolayer spectra are explained by the adsorbate bonding to the substrate. A connection to the electronic coupling in dye-sensitized electrochemical devices is made.