One- Pot Synthesis of Imidazolyl Isoquinolines under a PalladiumCatalyzed C-H Activation/Annulation (CHAA) Reaction
One- Pot Synthesis of Imidazolyl Isoquinolines under a PalladiumCatalyzed C-H Activation/Annulation (CHAA) Reaction
复制标题
钯催化 C-H 活化/成环 (CHAA) 反应一锅法合成咪唑基异喹啉
DOI：
10.1055/s-0036-1588101
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发表时间：
2017
影响因子：
2.6
通讯作者：
Huang Jianhui
中科院分区：
文献类型：
--
作者：
Zhu Ranran;Wang Yuntao;Liu Jialin;Wang Qing;Huang Jianhui
微波辅助钯催化一锅C-H活化/成环（CHAA）方案已被开发用于合成咪唑并[2,1-a]异喹啉和苯并[4,5]咪唑并[2,1-a]异喹啉。进一步的N-烷基化用于制备一系列相应的异喹啉鎓盐也已得到证实。已经研究了这些异喹啉的荧光特性。
A microwave-assisted Pd-catalyzed one-pot C–H activation/annulation (CHAA) protocol has been developed for the synthesis of imidazo[2,1-a]isoquinolines and benzo[4,5]imidazo[2,1-a]isoquinolines. FurtherN-alkylation for the preparation of a series of the corresponding isoquinolium salts has also been demonstrated. The fluorescent properties of these isoquinolines have been studied.