Dichlorido{1-[N-(5-chloro-2-oxidophen-yl)carboximido-yl]naphthalen-2-olato-κO,N,O'}(methanol-κO)tin(IV).
Dichlorido{1-[N-(5-chloro-2-oxidophen-yl)carboximido-yl]naphthalen-2-olato-κO,N,O'}(methanol-κO)tin(IV).
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DOI：
10.1107/s160053681200390x
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发表时间：
2012-03-01
期刊：
影响因子：
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通讯作者：
Mirtamizdoust B
中科院分区：
文献类型：
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作者：
Shahverdizadeh GH;Ng SW;Tiekink ER;Mirtamizdoust B
在标题配合物[Sn（C17 H10 ClNO 2）Cl 2（CH 3OH）]中，SnIV原子具有由二价阴离子的O，N，O′-供体、两个Cl原子和甲醇O原子限定的扭曲八面体构型。六元螯合环具有半椅构象，Sn原子位于由其余原子限定的平面外0.449（4）°（r.m.s.）。 偏差= 0.0238 Ω）。 超分子螺旋链沿着[100]，通过O-H-O氢键介导，在晶体堆积中具有特征。链通过C-H-O、C-H-Cl和π-π [质心-质心距离= 3.598（2）π]相互作用连接。
In the title complex, [Sn(C17H10ClNO2)Cl2(CH3OH)], the SnIV atom features a distorted octahedral geometry defined by the O,N,O′-donors of the dianion, two Cl atoms and the methanol O atom. The six-membered chelate ring has a half-chair conformation with the Sn atom lying 0.449 (4) Å out of the plane defined by the remaining atoms (r.m.s. deviation = 0.0238 Å). Supramolecular helical chains along [100], mediated by O—H⋯O hydrogen bonds, feature in the crystal packing. Chains are linked by C—H⋯O, C—H⋯Cl and π–π [centroid–centroid distance = 3.598 (2) Å] interactions.