Highly diastereoselective synthesis of orthoquinone monoketals through lambda3-iodane-mediated oxidative dearomatization of phenols.
Highly diastereoselective synthesis of orthoquinone monoketals through lambda3-iodane-mediated oxidative dearomatization of phenols.
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DOI：
10.1002/anie.200705816
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发表时间：
2008-04
影响因子：
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通讯作者：
L. Pouységu;S. Chassaing;Delphine Dejugnac;Anne-Marie Lamidey;K. Miqueu;J. Sotiropoulos;S. Quideau
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文献类型：
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作者：
L. Pouységu;S. Chassaing;Delphine Dejugnac;Anne-Marie Lamidey;K. Miqueu;J. Sotiropoulos;S. Quideau
邻苯二酚单缩酮A和邻苯二酚B是环己-2，4-二烯酮的衍生物，具有很好的反应活性，可用于构建复杂的分子结构。它们的共轭二烯酮单元及其含氧官能团的邻近位置构成了一种独特的结构安排，可以迅速转化为各种多氧(多)环系统(方案1)。
Orthoquinone monoketals A and orthoquinols B are cyclohexa-2,4-dienone derivatives with valuable reactivity features for the construction of complex molecular architectures. Their conjugated dienone unit and the vicinal positioning of their oxygenated functionalities constitute a unique structural arrangement that can be transformed rapidly into various kinds of polyoxygenated (poly)cyclic systems (Scheme 1).