Qualitative analysis of vibration-rotation hamiltonians for spherical top molecules
Qualitative analysis of vibration-rotation hamiltonians for spherical top molecules
复制标题
球形顶部分子振动-旋转哈密顿量的定性分析
DOI：
10.1080/00268978800100891
复制
发表时间：
1988
影响因子：
1.7
通讯作者：
B. Zhilinskií
中科院分区：
文献类型：
--
作者：
D. Sadovskií;B. Zhilinskií
提出了一种定性分析简并或准简并振动态群转动结构的新方法。该方法基于共振振动态的量子描述，并在描述这些态的旋转结构时使用经典方法。该方法用于研究四面体ab4分子的二重和三重简并振动态的旋转结构，以及28SiH4的v1， v3双偶结构。分析的总体方案由计算机实现。
A new approach to the qualitative analysis of the rotational structure of a group of degenerate or quasidegenerate vibrational states is proposed. The approach is based on a quantum description of resonant vibrational states and on using classical methods when describing the rotational structure of these states. The approach is used for studying the rotational structure of two- and three-fold degenerate vibrational states of the tetrahedral AB 4 molecule as well as for studying the v 1, v 3 diad of 28SiH4. The general scheme of the analysis is realized by computer.