Hyperchromic Effect of Silyl Groups on the UV-Visible Spectrum of 5,10,15,20-Tetraphenylporphyrin
Hyperchromic Effect of Silyl Groups on the UV-Visible Spectrum of 5,10,15,20-Tetraphenylporphyrin
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DOI：
10.1246/cl.2009.324
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发表时间：
2009-04-05
影响因子：
1.6
通讯作者：
Matsumoto, Hideyuki
中科院分区：
文献类型：
--
作者：
Kyushin, Soichiro;Yoshimura, Kimio;Matsumoto, Hideyuki
测量了5,10,15,20-四(4-甲硅烷基苯基)卟啉和5,10,15,20-四(3,5-二甲硅烷基苯基)卟啉的紫外-可见光谱。发现甲硅烷基对5,10,15,20-四苯基卟啉的Soret带和Q带具有增色作用。
UV-visible spectra of 5,10,15,20-tetrakis(4-silylphenyl)porphyrins and 5,10,15,20-tetrakis(3,5-disilylphenyl)porphyrins were measured. Silyl groups were found to have a hyperchromic effect on the Soret band and the Q band of 5,10,15,20-tetraphenylporphyrin.